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O Br2 O HOAc Br acetone bromoacetone We discussed resolution, the separation of enantiomers by the formation of diastereoisomers with an optically active resolving agent, in Chapter 16.
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3 This can be rewritten in terms of three quantities, the Hubble constant, which defines the rate of expansion, H(t) a ̇(t)H0 a ̇0a(t) a0 (11-26) (11-27) the deceleration parameter, a negative acceleration rate, q(t) aa ̈q0 a0 ̈a0 a ̈0 1a ̇ 2 a ̇ 20 a 0 H 02 and jerk, the rate at which the acceleration changes, 1.
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1 Nuclide 3H(T) 14C 22Na 24Na 32P 33P 35S 36Cl 45Ca 47Ca 51Cr 54Mn 55Fe 59Fe 57Co 60Co 63Ni 65Zn 75Se 86Rb 85Sr 99Mo99Tcm 106Ru 110Agm 109Cd 111In 125I 131I 137Cs 153Gd 201Tl 210Pb Commonly Used Tracers Method of Productiona R R C R R R R R R R R R R R C R R C,R R R R,C F F R C C R R F R C R Half-Life 12. However, by the triangle inequality, dðc1;wÞ14dðw;c2Þ14r implies that dðc1;c2Þ2r, guaranteeing that no such situation can occur when 2r d.
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1040 SECTION XIII GENETIC BASIS OF CONGENITAL MALFORMATIONS Anatomical region or system Craniofacial Musculoskeletal Urogenital Miscellaneous Radiographic Features Table 115-1 Primary Clinical and Radiographic Features of FGDY Clinical features Broad forehead, abnormally formed ears, hypertelorism, down-slanted palpebral fissures, ptosis, maxillary hypoplasia, anteverted nostrils, hypodontia and malocclusion (cleft lip and palate, enamel hypoplasia)a Disproportionate short stature, distally shortened limbs and brachydactyly, pectus excavatum, soft tissue syndactyly of the digits, interphalangeal joint hypermobility, camptodactyly and clinodactyly, broad feet, inguinal hernias (single palmar crease, abnormal dermatoglyphics) Shawl and bifid scrotum, crytorchidism (hypospadius, renal hypoplasia) Mild-to-moderate mental retardation, strabismus, growth hormone deficiency (congenital heart defects) Spina bifida occulta, odontoid hypoplasia, cervical vertebral defects and ligamentous laxity, calcified intervertebral disks, additional ribs, hypoplastic phalanges, retarded bone age (osteochondritis dissecans) aItems in parentheses are less commonly observed.
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